經修飾多孔有機骨架及其製備方法、多孔有機骨架複合物及其製備方法

專利類型

發明

專利國別 (專利申請國家)

中華民國

專利申請案號

107105647

專利證號

I 641613

專利獲證名稱

經修飾多孔有機骨架及其製備方法、多孔有機骨架複合物及其製備方法

專利所屬機關 (申請機關)

中原大學

獲證日期

2018/11/21

技術說明

一種經修飾多孔有機骨架的製備方法，包含提供一混合溶液以及進行一修飾步驟。混合溶液包含多孔有機骨架、複數個基團供體以及溶劑，其中多孔有機骨架包含複數個第一配位基，各第一配位基包含至少一四嗪基團，各基團供體包含反應基團及修飾基團，所述反應基團與所述修飾基團共價連接，且所述反應基團為烯基、炔基、醛基、酮基或其組合。修飾步驟中，反應基團與四嗪基團反應，使修飾基團與多孔有機骨架共價結合以獲得經修飾多孔有機骨架。藉此，經修飾多孔有機骨架的製備方法具有簡單的優點，並有利於擴大多孔有機骨架的應用範圍。 A method for manufacturing a modified porous organic framework includes steps as follows. A mixed solution is provided, and a modifying step is conducted. The mixed solution includes the porous organic framework, a plurality of group donors and a solvent. The porous organic framework includes a plurality of first ligands. Each of the first ligands includes at least one tetrazine group. Each of the group donors includes a reactive group and a modifying group which are covalently connected with each other. The reactive group is an alkenyl group, an alkynyl group, an aldehyde group, a ketone group or a combination thereof. In the modifying step, the reactive group is reacted with the tetrazine group, so that the modifying group is covalently connected to the porous organic framework so as to obtain the modified porous organic framework. As such, the method for manufacturing the modified porous organic framework has advantages of simplicity, and is favorable for broadening the application of the porous organic framework.

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